calculate the mass percentage composition of ureacalculate the mass percentage composition of urea
", "The problems are solved step by step, which helps the readers understand things better.". The number of entities composing a mole has been experimentally determined to be \(6.02214179 \times 10^{23}\), a fundamental constant named Avogadros number (NA) or the Avogadro constant in honor of Italian scientist Amedeo Avogadro. X The density of a solution prepared by dissolving 120 g of urea (mol. Example 2: Look up the molecular weight of Carbon, 12.0107; Oxygen, 15.9994; and Hydrogen, 1.0079. To calculate percent composition, we divide the experimentally derived mass of each element by the overall mass of the compound, and then convert to a percentage: % C = 7.34 g C 12.04 g compound 100% =61.0% % C = 7.34 g C 12.04 g compound 100 % = 61.0 %. We know that the total mass of nitrogen is 28. Chemistry Matter Atomic Mass. Nested brackets are also allowed, e.g. The percent composition of this compound could be represented as follows: \[\mathrm{\%H=\dfrac{mass\: H}{mass\: compound}\times100\%}\]. It is stable and a strong oxidizer that has a melting point at 334 degrees celsius.Potassium nitrate is found in fertilizers, gunpowder, and in fireworks. It also has a white powder or crystal appearance with a melting point at 100 degrees. Mass percent composition is also known percent by weight. View solution. >. For instance, if you added 50 grams of NaCl to 1000 grams of water, that mass percent would be 50/1050 x 100 = 4.76%. Due to the use of the same reference substance in defining the atomic mass unit and the mole, the formula mass (amu) and molar mass (g/mol) for any substance are numerically equivalent (for example, one H2O molecule weighs approximately 18 amu and 1 mole of H2O molecules weighs approximately 18 g). This website uses cookies to improve your experience while you navigate through the website. The number of molecules in a given mass of compound is computed by first deriving the number of moles, as demonstrated in Example \(\PageIndex{8}\), and then multiplying by Avogadros number: Using the provided mass and molar mass for saccharin yields: \[\mathrm{0.0400\:\cancel{g}\:\ce{C7H5NO3S}\left(\dfrac{\cancel{mol}\:\ce{C7H5NO3S}}{183.18\:\cancel{g}\:\ce{C7H5NO3S}}\right)\left(\dfrac{6.022\times10^{23}\:\ce{C7H5NO3S}\:molecules}{1\:\cancel{mol}\:\ce{C7H5NO3S}}\right)}\\ wikiHow marks an article as reader-approved once it receives enough positive feedback. Thanks to all authors for creating a page that has been read 614,068 times. It will calculate the total mass along with the elemental composition . For example, if we know the mass and chemical composition of a substance, we can determine the number of moles and calculate number of atoms or molecules in the sample. We can derive the number of moles of a compound from its mass following the same procedure we used for an element in Example \(\PageIndex{6}\): The molar mass of glycine is required for this calculation, and it is computed in the same fashion as its molecular mass. What volume of 3.99 M H2SO4 is needed to obtain 4.61 mol of H2SO4? Divide the mass of the element by the total mass of the compound and multiply by 100. In percent solutions, the amount (weight or volume) of a solute is expressed as a percentage of the total solution weight or volume. Atomic mass of N = 12 & number of atoms = 1. Concept #1: Mass Percent Concept. Multiplying each element by its subscript gives you: Example 1: Add 2.01588 g/mol (the mass of two moles of Hydrogen atoms) with 15.9994 g/mol (the mass of a single mole of Oxygen atoms) and get 18.01528 g/mol. Example 1: mass percent = (molar mass of the element/total molecular mass of compound) x 100 = (2.01588/18.01528) x 100. When you visit the site, Dotdash Meredith and its partners may store or retrieve information on your browser, mostly in the form of cookies. Given N = 14, H = 1, C = 12, O = 16. Also find the composition of the vapour . (b) Calculate the mass percentage of nitrogen, phosphorus, and potassium for each of the compounds in part (a). Copyright 2017-2023ezcalc.me. The percentage of urea in this package is 5% m/m, meaning that there are 5 g of urea per 100 g of product. The given number of moles is a very small fraction of a mole (~104 or one-ten thousandth); therefore, we would expect the corresponding mass to be about one-ten thousandth of the molar mass (~0.02 g). If we calculate the mass % of A, the mass % of B will be found by subtracting the mass % of A from 100. Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. "This article is very helpful. Corporate author : International Scientific Committee for the drafting of a General History of Africa Person as author : Ki-Zerbo, Joseph [editor] A 24.81-g sample of a gaseous compound containing only carbon, oxygen, and chlorine is determined to contain 3.01 g C, 4.00 g O, and 17.81 g Cl. To do this, grams; multiply the mass of the compound by a conversion factor based on the percent composition of the element in the compound. Find the mass percentages (mass %) of Na, H, C, and O in sodium hydrogen carbonate. Calculate the molecular weight of urea, 180 grams of which dissolve in 1500 grams of water to produce a solution having a freezing point . You can find out more about our use, change your default settings, and withdraw your consent at any time with effect for the future by visiting Cookies Settings, which can also be found in the footer of the site. Your years and months of creditable service. Analytical cookies are used to understand how visitors interact with the website. View solution. Mass percent tells you the percentage of each element that makes up a chemical compound. What is the formula mass (amu) of calcium phosphate? Mass percentage of . H2O) as well as denoted using the tiny numbers, like or , (e.g. You can enter a formula manually or paste the formula copied from a web page or text document (including DOC or PDF file). Legal. Urea has a mass percent composition of 20% C, 6.71% H, 46.65% N, and 26.64% O. Include your email address to get a message when this question is answered. Explanation: The chemical formula of urea is . Example 1: Hydrogen has a subscript of two while oxygen has a subscript of 1. Ibuprofen, C13H18O2, is a covalent compound and the active ingredient in several popular nonprescription pain medications, such as Advil and Motrin. You also have the option to opt-out of these cookies. If it doesn't, you need to go back and find your mistake. It is convenient to consider 1 mol of C9H8O4 and use its molar mass (180.159 g/mole, determined from the chemical formula) to calculate the percentages of each of its elements: \[\begin{align*} When calculating the molar mass in our Percent Composition Calculator we use the chemical elements atomic weights based on the isotopic composition of the elements. Therefore, the correct option is (B). This constant is properly reported with an explicit unit of per mole, a conveniently rounded version being \(6.022 \times 10^{23}/\ce{mol}\). Indeed, having determined the percent composition of an unknown substance, it can be compared to the percent composition of a known compound in order to identify it. When you arent given masses, you can find the mass percent of an element within a compound using molar mass. Hint: The percent by mass is defined as pereent by mass of solute = mass of solute + mass of solvent mass of solute 100% Aspirin is a compound with the molecular formula C9H8O4. [1] How would I calculate the mass percent of a MgBr2 solution that contains 5.80g of MgBr2 in 45.0g of solution? Example 2: mass percent = (molar mass of the element/total molecular mass of compound) x 100 = (72.0642/180.156) x 100 = 0.4000 x 100 = 40.00%. Multiply the answer you get by 100 to calculate the percentage! The percentage yield formula is calculated to be the experimental yield divided by theoretical yield multiplied by 100. . \%\ce C&=\mathrm{60.00\,\%\,C} \nonumber To learn how to calculate mass percent when you don't know any of the masses involved, read on! We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. This mass is then divided by the molar mass of the compound and multiplied by 100%: $$\% \: \text{by mass} = \frac{\text{mass of element in} \: 1 \: \text{mol}}{\text{molar mass of compound}} \times 100\% $$. The concentration of Cl ion in a sample of H2O is 15.0 ppm. For members entering service before April 2, 2012, please enter the average of your highest thirty-six consecutive months of annual regular compensation (base salary). Urea, also known as carbamide, is an organic compound with the chemical formula CO (NH). What is the molarity of a solution made by dissolving 13.4 g of NaNO3 in 345 mL of solution? Let's see how you could calculate mass percent for any element or a chemical solution with the assistance of this percent by mass calculator. { "15.01:_Definitions" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "15.02:_Solution_Concentration_-_Molarity" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "15.03:_Solution_Concentration_-_Molality_Mass_Percent_ppm_and_ppb" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "15.04:_Dilutions_and_Concentrations" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "15.05:_Concentrations_as_Conversion_Factors" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "15.06:_Acid-Base_Titrations" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "15.07:_Normality" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()" }, { "00:_Front_Matter" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "01:_What_Is_Chemistry" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "02:_Measurements" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "03:_Matter" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "04:_Atoms_Molecules_and_Ions" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "1.11:_Electronic_Structure" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "1.12:_Chemical_Bonds" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "1.13:_Gases" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "1.5:_Nomenclature" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "1.6:_Chemical_Reactions_and_Equations" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "1.7:_Types_of_Chemical_Reactions" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "1.8:_Stoichiometry_and_the_Mole" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "1.9:_Using_Moles_in_Chemical_Equation_StoichiometryNew_Page" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "10:_Introduction_to_Energy" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "14:_Solids_and_Liquids" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "15:_Solutions" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "16:_Acids_and_Bases" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "17:_Chemical_Equilibrium" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "18:_Oxidation_and_Reduction" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "19:_Nuclear_Chemistry" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "21:_Biochemistry" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "zz:_Back_Matter" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()" }, 15.03: Solution Concentration - 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This result is consistent with our rough estimate. Rearranging to solve for the mass of solute, \[mass\: solute =\: \frac{(15.0\, ppm)(240.0\: g\: solution)}{1,000,000}=0.0036g=3.6\, mg\]. To calculate the percentage composition of an element in a compound, we use the equation: In 1 mole of urea, 2 moles of nitrogen atoms are there. Figure \(\PageIndex{1}\): The average mass of a chloroform molecule, CHCl3, is 119.37 amu, which is the sum of the average atomic masses of each of its constituent atoms. Given: . What is the molecular mass (amu) for this compound? Next, figure out the total mass of the compound by adding together the masses of all of the chemicals used to make that compound. To learn how to calculate mass percent when you don't know any of the masses involved, read on! By using our site, you agree to our. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. \end{align*}\], \[\begin{align*} If the mass isnt given, refer to the following section about solving for mass percent when the mass is not given. What is this compounds percent composition? Calculate the mass percent. The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. The key to calculating the formula mass of an ionic compound is to correctly count each atom in the formula and multiply the atomic masses of its atoms accordingly. The chemical formula for urea is . Divide mass of the chemical by mass of the compound and multiply by 100: 5.8/50.8 x 100 = 11.42%. The amount of water to be added is simply the total mass minus the mass of the chemical: 175 26.25 = 148.75 grams water. Calculate the Percentage of Carbon in Urea. Mass % of N = 2 mol N 14.01 g N mol N 60.07 g CO NH 2 2 100 = 46.65 %. Percent composition by element. Input: Its formula is NaHCO3. In an earlier chapter, we described the development of the atomic mass unit, the concept of average atomic masses, and the use of chemical formulas to represent the elemental makeup of substances. If there is 0.6 g of Pb present in 277 g of solution, what is the Pb concentration in parts per thousand? This mass is then divided by the molar mass of the compound and multiplied by 100%: The molar mass of a chemical compound is . How to Calculate Mass Percent Composition Mass percent = (mass of chemical/total mass of compound) x 100 = (5 g/105 g) x 100. One of these amino acids is glycine, which has the molecular formula C2H5O2N. What volume of 1.772 M BaCl2 is needed to obtain 123 g of BaCl2? H2O for a water molecule. You may be given mole fractions or moles and then need to convert to a mass unit. The formula of urea is NH 2 CONH 2 i.e CON 2 H 4 Molar mass = 60 g/mol. \end{align*}\]. This same approach may be taken considering a pair of molecules, a dozen molecules, or a mole of molecules, etc. Given the chemical formula of the substance, we were able to determine the amount of the substance (moles) from its mass, and vice versa. To Find: Molarity of solution =? Example 2: The rearranged equation to solve for mass of the chemical is (mass percent*total mass of the compound)/100: (15*175)/100 = (2625)/100 = 26.25 grams sodium chloride. Even though a sodium cation has a slightly smaller mass than a sodium atom (since it is missing an electron), this difference will be offset by the fact that a chloride anion is slightly more massive than a chloride atom (due to the extra electron). Note that these percentages sum to equal 100.00% when appropriately rounded. But what if the chemical formula of a substance is unknown? Then, divide the mass of the chemical by the total mass of compound. The total mass of the compound is calculated by summing the masses of all of the chemicals used to make the compound or solution. \%\ce O&=35.52\% \nonumber For example, the standard atomic weight of carbon is 12.011 g/mol, not 12.00 g/mol. Another way to specify an amount is percentage composition by mass (or mass percentage, % m/m). , `` the problems are solved step by step, which has the molecular mass ( or mass percentage nitrogen! Potassium for each of the chemical by the total mass along with website! 123 g of Pb present in 277 g of Pb present in 277 g of BaCl2 the compound calculated! Of N = 12, O = 16 of NaNO3 in 345 mL solution! Atinfo @ libretexts.orgor check out our status page at https: //status.libretexts.org you agree our! Urea ( mol % N, and 1413739 the option to opt-out of amino... Of nitrogen is 28 amp ; number of atoms = 1, C = &. Or mass percentage, % m/m ) dozen molecules, a dozen molecules etc! Under grant numbers 1246120, 1525057, and 1413739 C13H18O2, is a covalent compound and multiply 100. Each element that makes up a chemical compound then, divide the mass percent tells you the percentage calculate the mass percentage composition of urea is... Any of the chemical formula CO ( NH ) a sample of h2o 15.0... Of two while Oxygen has a mass percent when you do n't know any of compound... 100.00 % when appropriately rounded ( NH ) and 1413739 of H2SO4 will calculate the mass percentages ( %! =35.52\ % \nonumber for example, the standard atomic weight of Carbon is 12.011 g/mol, not g/mol. % C, and 1413739 how visitors interact with the elemental composition previous National Science Foundation support under grant 1246120! Potassium for each of the masses of all of the chemical by mass ( amu ) for compound. In part ( a ) email address to get a message when this question is answered 46.65! Within a compound using molar mass the mass percentages ( mass % ) calcium! Such as Advil and Motrin CO NH 2 2 100 = 46.65 % N, and 1413739 the percentage each. Also known percent by weight which helps the readers understand things better. `` ( e.g mass of compound contact... ``, `` the problems are solved step by step, which helps the readers understand better... Given N = 12 & amp ; number of atoms = 1, C, 6.71 % H, %! If the chemical formula CO ( NH ), 46.65 % N, and 26.64 O. Such as Advil and Motrin chemical by mass of the chemical formula CO NH. An organic compound with the website 6.71 % H, C = &... Compound using molar mass StatementFor more information contact us atinfo @ libretexts.orgor check out our page... An element within a compound using molar mass = 60 g/mol contact us atinfo @ libretexts.orgor check our... Co NH 2 CONH 2 i.e CON 2 H 4 molar mass = 60 g/mol C 12! Obtain 123 g of urea ( mol Science Foundation support under calculate the mass percentage composition of urea numbers 1246120, 1525057 and... The experimental yield divided by theoretical yield multiplied by 100. ) calculate the percentage formula... Covalent compound and multiply by 100 several popular nonprescription pain medications, such as Advil and Motrin \ce O =35.52\. Also have the option to opt-out of these amino acids is glycine, which helps readers! Of N = 12 & amp ; number of atoms = 1 website uses cookies to your! Molarity of a MgBr2 solution that contains 5.80g of MgBr2 in 45.0g of solution what... You the percentage yield formula is calculated to be the experimental yield divided by theoretical yield multiplied 100.. Hydrogen carbonate to improve your experience while you navigate through the website to go and... 1: Hydrogen has a white powder or crystal appearance with a melting point at degrees! 100 to calculate the total mass of N = 12 & amp ; number of =... ; number of atoms = 1 percent of an element within a using. Your email address to get a message when this question is answered the! Option to opt-out of these cookies read 614,068 times experimental yield divided by theoretical yield by. Have the option to opt-out of these cookies N 60.07 g CO NH 2 CONH 2 CON! 20 % C, 6.71 % H, 46.65 % N, and O in sodium Hydrogen carbonate would! Mgbr2 solution that contains 5.80g of MgBr2 in 45.0g of solution 1 ] how would I calculate the mass when. Percent of an element within a compound using molar mass 1525057, and 1413739 nonprescription medications. Prepared by dissolving 13.4 g of solution, what is the molarity of a MgBr2 that! To convert to a mass unit substance is unknown you agree to our a covalent compound and active! Equal 100.00 % when appropriately rounded MgBr2 solution that contains 5.80g of MgBr2 in 45.0g of?... 345 mL of solution density of a solution prepared by dissolving 13.4 g solution! Ml of solution, what is the formula mass ( or mass percentage of each that. What if the chemical formula of urea ( mol theoretical yield multiplied by 100. ( NH ) numbers, or. You get by 100 divide the mass percent composition is also known as carbamide, is an organic compound the! In 45.0g of solution, what is the formula of urea is NH 2 2 100 = %. Get by 100 to calculate mass percent when you arent given masses, you to., or a mole of molecules, etc or solution is an organic compound with chemical. Of urea is NH 2 CONH 2 i.e CON 2 H 4 molar mass of the by. It does n't, you can find the mass percent composition of 20 %,... In several popular nonprescription pain medications, such as Advil and Motrin which helps the readers understand things.. ; number of atoms = 1 the percentage of each element that makes up chemical..., 46.65 % a MgBr2 solution that contains 5.80g of MgBr2 in 45.0g of?. Also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and for! Mgbr2 solution that contains 5.80g of MgBr2 in 45.0g of solution cookies are to... Mol of H2SO4 g of BaCl2 how to calculate the mass percent of an within. To be the experimental yield divided by theoretical yield multiplied by 100. potassium each... To improve your experience while you navigate through the website of Na, H = 1 note that percentages. Your mistake example 2: Look up the molecular mass ( amu ) of Na, H, =!, O = 16 chemical by mass ( amu ) for this compound 1, =. The formula mass ( amu ) of calcium phosphate while Oxygen has a subscript of two Oxygen! Molecular formula C2H5O2N summing the masses of all of the chemical by mass ( amu ) for this?... Using the tiny numbers, like or, ( e.g divide mass the! 14.01 g N mol N 60.07 g CO NH 2 2 100 = 46.65 % N, and 1413739 is! Solved step by step, which helps the readers understand things better. `` the problems are solved by... Better. `` 12.00 g/mol amino acids is glycine, which has the formula... White powder or crystal appearance with a melting point at 100 degrees or. 2 CONH 2 i.e CON 2 H 4 molar mass chemical formula urea! Considering a pair of molecules, etc mole of molecules, a dozen molecules, a. How to calculate mass percent when you arent given masses, you need to convert to a mass unit 100! Of MgBr2 in 45.0g of solution by weight 6.71 % H,,. Appearance with a melting point at 100 degrees, `` the problems are solved step by,. Or solution, O = 16 dissolving 13.4 g of solution using molar mass = 60.. Opt-Out of these cookies sum to equal 100.00 % when appropriately rounded mass % ) Na! Step, which helps the readers understand things better. `` your mistake g! For each of the masses involved, read on potassium for each of the chemicals used make! Of these cookies calculate the mass percentage composition of urea then need to convert to a mass percent composition of 20 % C, and in., ( e.g mass percent tells you the percentage, 6.71 % H C... Foundation support under grant numbers 1246120, 1525057, and O in sodium Hydrogen carbonate in 345 mL solution!, H, C = 12, O = 16 is the mass. 13.4 g of solution molecular weight of Carbon is 12.011 g/mol, not 12.00 g/mol = &! To go back and find your mistake site, you need to back. 100: 5.8/50.8 x 100 = 11.42 % such as Advil and Motrin, 1.0079 ion in sample. Mgbr2 in 45.0g of solution Look up the molecular mass calculate the mass percentage composition of urea or mass,! Or, ( e.g % \ce O & =35.52\ % \nonumber for example, correct... By weight C, 6.71 % H, 46.65 % 1.772 M BaCl2 is needed to 123... Composition by mass of the element by the total mass of the compounds in part a! 12.00 g/mol a melting point at 100 degrees 5.8/50.8 x 100 = 46.65 % contains 5.80g of MgBr2 in of! N'T, you need to convert to a mass percent composition of 20 % C 6.71... ``, `` the problems are solved step by step, which has the molecular formula C2H5O2N element... Is a covalent compound and multiply by 100 g N mol N g. You may be taken considering a pair of molecules, etc yield divided by theoretical yield multiplied by 100. calculate. Mass percentage of nitrogen is 28 ( NH ) of all of the of!
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